Lesson
The theory — Diffraction Grating
A diffraction grating is a surface ruled with many parallel lines a distance d apart, which either transmit or reflect light. Light leaving neighbouring lines at an angle θ has travelled paths that differ by d sin θ, so the waves from all the lines arrive in step, and the light is bright, only where d sin θ = mλ, for a whole number m called the order. Everywhere else the contributions of N lines cancel almost completely; the first dark angle beside each bright one is only about λ/(N d cos θ) away. Two wavelengths come out as separate lines when the resolving power R = mN is at least λ/Δλ.
What each symbol means
d- the distance between neighbouring lines, 1 mm divided by the number of lines per millimetre
λ- the wavelength of the light, in the air after the grating
m- the order, a whole number; m = 0 is the straight-through beam, and only orders with mλ < d exist
N- the number of lines the beam actually covers, not the number ruled on the grating
R- resolving power, mN: the smallest wavelength difference the order separates is λ/R
- Assumes
- Light of a single wavelength arriving head-on, from a source far enough away and a screen far enough away that every line sends out waves at the same angle. Lines narrow enough that each spreads its light over the whole half-space, so every order is equally bright. All N lit lines equally lit. A reflection grating, like a disc, follows the same formula at normal incidence as a transmission grating does.
- Breaks when
- Real lines have a width a, and the light from one line is itself a single-slit pattern that dims the higher orders and wipes out any order that lands on one of its zeros: with a = d/2, every even order is missing. Light arriving at an angle θᵢ obeys d(sin θᵢ + sin θ) = mλ instead, which lets wavelengths up to 2d diffract when the light arrives at a grazing angle; that is why a Blu-ray disc tilted to the light does show some colour. And a beam of finite width lights its central lines more strongly than its edges, which softens the side lobes without moving the orders.
Problem solved in full
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Which orders of white light overlap? 5 steps
White light, 400 to 700 nm, falls head-on on a grating of 300 lines per millimetre. Where does each order's spectrum begin and end, which of them overlap, and would a finer grating keep them apart? Press 300 lines/mm, 600 lit to check the first step.
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The line spacing is 1 mm over 300, which the page prints:
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The first-order spectrum runs from the angle where violet satisfies d sin θ = λ to the angle where red does:
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The second order runs from 13.89° to 24.83°, so there is a clear gap between it and the first:
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The third order begins at 21.10°, before the second has ended. Where its violet lands, the second order is showing 600 nm orange light, because 3 × 400 = 2 × 600:
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Orders m and m + 1 overlap when m times the red end is longer than m + 1 times the violet end. The spacing d cancels:
Answer
The first order runs from 6.89° to 12.12° and stands alone. From the second order on, every spectrum runs into the one after it: the second's red end is at 24.83° and the third begins at 21.10°. No grating separates them, because the condition m·700 > (m + 1)·400 has no d in it. A finer grating spreads the orders further and leaves fewer of them, and the second order escapes only when the grating is so fine that no third order is left to meet it. The first order is clear only because visible light spans less than an octave, 700/400 = 1.75. A spectrometer that works in a higher order puts a filter in front of the grating to cut off the light from the neighbouring orders, an order-sorting filter.
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References (3)
- The resolving power of a grating, R = mN with N the number of lines illuminated, from the Rayleigh criterion applied to the diffraction maxima, and the sodium doublet as the standard benchmark: R. Nave, "Resolvance of Grating." HyperPhysics, Department of Physics and Astronomy, Georgia State University.
- The two yellow lines of neutral sodium, the D lines, at 5889.950 and 5895.924 Å in air, which the sodium preset uses: J. E. Sansonetti and W. C. Martin, "Handbook of Basic Atomic Spectroscopic Data", NIST Standard Reference Database 108, table of Strong Lines of Sodium (Na). National Institute of Standards and Technology.
- The DVD standard, which fixes the track pitch at 0.74 µm, the spacing that makes a DVD a grating with room for only one order of red light: Ecma International, Standard ECMA-267, "120 mm DVD - Read-Only Disk", 3rd edition, April 2001.