Subtracting the mean and dividing by the standard deviation shifts and stretches a distribution; it cannot change its shape. Standardise something strongly skewed and it comes out exactly as skewed as it went in. The z itself survives that — it still honestly reports how many standard deviations out you are — but the percentile row does not, because it is computed as Φ(z) and Φ is the normal curve. How much work is that assumption doing? For a normal distribution 4.55% of values sit beyond ±2. For an arbitrary distribution, all Chebyshev's inequality will promise is at most 25%. The normal assumption is buying you a factor of five and a half at z = 2, so it is worth knowing whether you have earned it before quoting the percentile.